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Inside Back Cover: Palladium(II)‐Catalyzed Dehydroboration via Generation of Boron Enolates (Chem. Eur. J. 52/2016)
Author(s) -
Sakamoto Yuki,
Amaya Toru,
Suzuki Takeyuki,
Hirao Toshikazu
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201604874
Subject(s) - catalysis , palladium , boron , chemistry , nonane , cover (algebra) , transformation (genetics) , combinatorial chemistry , medicinal chemistry , organic chemistry , mechanical engineering , biochemistry , engineering , gene
Transformation from ketones to α,β‐unsaturated ketones is an important reaction in organic synthesis. As a new method for this transformation, the Pd II ‐catalyzed dehydroboration of boron enolates generated from ketones and 9‐iodo‐9‐borabicyclo[3.3.1]nonane has been achieved, providing a synthetically versatile protocol. The Pd II compound employed in this reaction works catalytically in the presence of Cu(OAc) 2 . More information can be found in the Communication by T. Hirao et al. on page 18686 ff.