Ru‐Catalyzed Dehydrogenative C−O Bond Formation with Anilines and Phenols | Zendy

Heitz Christophe | Zendy; Jones Alexander W. | Zendy; Oezkaya Bünyamin S. | Zendy; Bub Christina L. | Zendy; LouillatHabermeyer MarieLaure | Zendy; Wagner Victoria | Zendy; Patureau Frederic W. | Zendy

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Ru‐Catalyzed Dehydrogenative C−O Bond Formation with Anilines and Phenols

Author(s) -

Heitz Christophe,

Jones Alexander W.,

Oezkaya Bünyamin S.,

Bub Christina L.,

LouillatHabermeyer MarieLaure,

Wagner Victoria,

Patureau Frederic W.

Publication year - 2016

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201604764

Subject(s) - catalysis , phenols , chemistry , bond , medicinal chemistry , organic chemistry , business , finance

The Ru catalyzed cross‐dehydrogenative C−O bond formation between anilines and phenols is described and discussed. The exclusive C−O versus C−N bond‐formation selectivity, moreover in the absence of chelating–assisting directing groups and while leaving the N−H position untouched, is a remarkable feature of this metal‐catalyzed radical cross‐dehydrogenative coupling.

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