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Ru‐Catalyzed Dehydrogenative C−O Bond Formation with Anilines and Phenols
Author(s) -
Heitz Christophe,
Jones Alexander W.,
Oezkaya Bünyamin S.,
Bub Christina L.,
LouillatHabermeyer MarieLaure,
Wagner Victoria,
Patureau Frederic W.
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201604764
Subject(s) - catalysis , phenols , chemistry , bond , medicinal chemistry , organic chemistry , business , finance
The Ru catalyzed cross‐dehydrogenative C−O bond formation between anilines and phenols is described and discussed. The exclusive C−O versus C−N bond‐formation selectivity, moreover in the absence of chelating–assisting directing groups and while leaving the N−H position untouched, is a remarkable feature of this metal‐catalyzed radical cross‐dehydrogenative coupling.