Gold(III) Triggered Transformations of 22‐Methyl‐ m ‐benziporphyrin Involving an Effective Contraction of Benzene to Cyclopentadiene | Zendy

Hurej Karolina | Zendy; Pawlicki Miłosz | Zendy; LatosGrażyński Lechosław | Zendy

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Gold(III) Triggered Transformations of 22‐Methyl‐ m ‐benziporphyrin Involving an Effective Contraction of Benzene to Cyclopentadiene

Author(s) -

Hurej Karolina,

Pawlicki Miłosz,

LatosGrażyński Lechosław

Publication year - 2017

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201604458

Subject(s) - cyclopentadiene , benzene , chemistry , contraction (grammar) , yield (engineering) , medicinal chemistry , stereochemistry , organic chemistry , materials science , metallurgy , catalysis , biology , endocrinology

A structurally prearranged carbaporphyrin, 22‐methyl‐ m ‐benziporphyrin, provided the perfect macrocyclic platform to form gold(III) 22‐methyl‐ m ‐benziporphyrin, which facilitates the specific m ‐benzene ring contraction yielding gold(III) 21‐methyl 21‐carbaporphyrin with remarkably high yield.

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