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Gold(III) Triggered Transformations of 22‐Methyl‐ m ‐benziporphyrin Involving an Effective Contraction of Benzene to Cyclopentadiene
Author(s) -
Hurej Karolina,
Pawlicki Miłosz,
LatosGrażyński Lechosław
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201604458
Subject(s) - cyclopentadiene , benzene , chemistry , contraction (grammar) , yield (engineering) , medicinal chemistry , stereochemistry , organic chemistry , materials science , metallurgy , catalysis , biology , endocrinology
A structurally prearranged carbaporphyrin, 22‐methyl‐ m ‐benziporphyrin, provided the perfect macrocyclic platform to form gold(III) 22‐methyl‐ m ‐benziporphyrin, which facilitates the specific m ‐benzene ring contraction yielding gold(III) 21‐methyl 21‐carbaporphyrin with remarkably high yield.