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Decarboxylative Aminomethylation of Aryl‐ and Vinylsulfonates through Combined Nickel‐ and Photoredox‐Catalyzed Cross‐Coupling
Author(s) -
Fan Lulu,
Jia Jiaqi,
Hou Hong,
Lefebvre Quentin,
Rueping Magnus
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201604452
Subject(s) - aryl , nickel , catalysis , chemistry , cleavage (geology) , bond cleavage , photoredox catalysis , combinatorial chemistry , organic chemistry , materials science , photocatalysis , alkyl , fracture (geology) , composite material
A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C−O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.

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