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Nucleophilic Additions to Coordinated 1,10‐Phenanthroline: Intramolecular, Intermolecular, Reversible, and Irreversible
Author(s) -
Arévalo Rebeca,
Menéndez M. Isabel,
López Ramón,
Merino Isabel,
Riera Lucía,
Pérez Julio
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201604438
Subject(s) - intramolecular force , phenanthroline , intermolecular force , nucleophile , chemistry , photochemistry , medicinal chemistry , stereochemistry , crystallography , molecule , organic chemistry , catalysis
KN(SiMe 3 ) 2 reacts with [Re(CO) 3 (phen)(PMe 3 )]OTf via reversible addition to the phen ligand and irreversible deprotonation of the PMe 3 ligand followed by intramolecular attack to phen by the deprotonated phosphane, whereas MeLi irreversibly adds to phen. The addition of MeLi has been shown to be intermolecular, unlike previously known nucleophilic additions to pyridines.