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Inside Back Cover: Reducing Capsule Based on Electron Programming: Versatile Synthesizer for Size‐Controlled Ultra‐Small Metal Clusters (Chem. Eur. J. 46/2016)
Author(s) -
Kambe Tetsuya,
Imaoka Takane,
Yamamoto Kimihisa
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201604371
Subject(s) - dendrimer , cover (algebra) , metal , materials science , reducing agent , electron , nanotechnology , reduction (mathematics) , chemical engineering , physics , engineering , polymer chemistry , metallurgy , mechanical engineering , mathematics , geometry , quantum mechanics
Reducing template dendritic polyphenylazomethines (RTDPAs) with a specific number of reducing electrons were achieved by appropriately placing BH 3 units in the dendrimer. The RTDPA acted as a synthesizer for monodispersed and ultra‐small metal clusters by the fine‐controlled and rapid‐reduction process. This method has expanded the metal variation of the controlled clusters. More information can be found in the Communication by K. Yamamoto et al. on page 16406 ff.