Premium
Back Cover: Ate Complexes in Iron‐Catalyzed Cross‐Coupling Reactions (Chem. Eur. J. 44/2016)
Author(s) -
Parchomyk Tobias,
Koszinowski Konrad
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201604265
Subject(s) - catalysis , electrospray ionization , fragmentation (computing) , coupling (piping) , chemistry , reactivity (psychology) , mass spectrometry , ionization , cover (algebra) , coupling reaction , combinatorial chemistry , chemical physics , materials science , organic chemistry , ion , computer science , chromatography , engineering , medicine , mechanical engineering , alternative medicine , pathology , metallurgy , operating system
Find the way to cross‐coupling and keep clear of homo‐coupling! Iron catalysts are promising candidates for this task. Probing these catalysts by electrospray‐ionization mass spectrometry permits the detection of numerous organoferrate anions. Gas‐phase fragmentation experiments on these complexes can determine their microscopic reactivity, thus providing detailed insight into the mechanism of iron‐catalyzed cross‐coupling reactions. More information can be found in the Communication by K. Koszinowski et al. on page 15609 ff.