Molecular E(CN) 3  (E=Sb, Bi) Species Synthesized from Ionic Liquids as Solvates | Zendy

Arlt Sören | Zendy; Harloff Jörg | Zendy; Schulz Axel | Zendy; Stoffers Alrik | Zendy; Villinger Alexander | Zendy

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Molecular E(CN) 3 (E=Sb, Bi) Species Synthesized from Ionic Liquids as Solvates

Author(s) -

Arlt Sören,

Harloff Jörg,

Schulz Axel,

Stoffers Alrik,

Villinger Alexander

Publication year - 2016

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201603849

Subject(s) - ionic liquid , trifluoromethanesulfonate , pnictogen , hexafluorophosphate , chemistry , recrystallization (geology) , medicinal chemistry , ionic bonding , ion , organic chemistry , catalysis , physics , paleontology , superconductivity , quantum mechanics , biology

The heavy pnictogen tricyanides, E(CN) 3 (E=Sb, Bi), were synthesized from EF 3 and Me 3 SiCN in ionic liquids, for example, 1‐butyl‐3‐methylimidazolium trifluoromethanesulfonate ([BMIm][OTf]), which prevents the oligomerization of the molecular E(CN) 3 species by formation of [BMIm][E(CN) 3 (OTf)] salts in solution. Recrystallization of [BMIm][E(CN) 3 (OTf)] from THF led to the isolation and full characterization of the molecular species E(CN) 3 ⋅ 2 THF.

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