Palladium‐Catalyzed Regiodivergent Substitution of Propargylic Carbonates | Zendy

Locascio Theresa M. | Zendy; Tunge Jon A. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Palladium‐Catalyzed Regiodivergent Substitution of Propargylic Carbonates

Author(s) -

Locascio Theresa M.,

Tunge Jon A.

Publication year - 2016

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201603481

Subject(s) - regioselectivity , palladium , catalysis , denticity , ligand (biochemistry) , acetonitrile , chemistry , combinatorial chemistry , stereochemistry , substitution (logic) , medicinal chemistry , organic chemistry , computer science , crystal structure , receptor , biochemistry , programming language

The palladium(0)‐catalyzed, ligand‐controlled, regioselective addition of diaryl acetonitrile pronucleophiles to propargylic carbonates is reported. Selective formation of either terminal 1,3‐dienyl or propargylated products is proposed to arise from a change in reaction mechanism controlled by the denticity of the coordinating ligand.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research