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Inside Cover: Assembly of Multi‐Phthalocyanines on a Porphyrin Template by Fourfold Rotaxane Formation (Chem. Eur. J. 35/2016)
Author(s) -
Yamada Yasuyuki,
Kato Tatsuhisa,
Tanaka Kentaro
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201602993
Subject(s) - rotaxane , porphyrin , crown ether , phthalocyanine , chemistry , polymer chemistry , brush , ether , photochemistry , materials science , crystallography , supramolecular chemistry , organic chemistry , crystal structure , ion , composite material
Self‐organization of phthalocyanines has been programmed on a porphyrin template. Two phthalocyanines with four peripheral crown ether units are stacked cofacially on a porphyrin bearing four alkylammonium chains, in accordance with the number of ammonium groups on the side chain, through fourfold rotaxane formation. Significant electronic interaction is observed between the closely stacked phthalocyanines. More information can be found in the Full Paper by K. Tanaka, et al. on page 12371 ff.