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Inside Cover: Covalent Immobilization of Polyoxotungstate on Alumina and Its Catalytic Generation of Sulfoxides (Chem. Eur. J. 32/2016)
Author(s) -
Hong Lanlan,
Win Pyaesone,
Zhang Xuan,
Chen Wei,
Miras Haralampos N.,
Song YuFei
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201602961
Subject(s) - polyoxometalate , catalysis , cover (algebra) , covalent bond , chemistry , combinatorial chemistry , chip , nanotechnology , chemical engineering , materials science , organic chemistry , computer science , engineering , mechanical engineering , telecommunications
The structural and chemical stability of immobilized polyoxometalate (POM)‐containing catalysts are crucial for their industrial application. A highly stable catalyst was prepared by linking [α‐P 2 W 15 O 56 ] 12− clusters with a spherical γ‐Al 2 O 3 support. In the cover image, the [α‐P 2 W 15 O 56 ] 12− clusters are depicted as a functional device immobilized on a basal chip (representing the γ‐Al 2 O 3 support). As a result, different signals can get through the functional devices and be processed to give a signal (the product). Such multifunctional catalysts can be designed on a smart chip to catalyze multistep reactions in the near future. More information can be found in the Full Paper by W. Chen, Y.‐F. Song et al. on page 11232 ff.