Visible‐Light‐Induced Trifluoromethylation of Isonitrile‐Substituted Methylenecyclopropanes: Facile Access to 6‐(Trifluoromethyl)‐7,8‐Dihydrobenzo[ k ]phenanthridine Derivatives | Zendy

Yuan YuChao | Zendy; Liu HouLu | Zendy; Hu XuBo | Zendy; Wei Yin | Zendy; Shi Min | Zendy

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Visible‐Light‐Induced Trifluoromethylation of Isonitrile‐Substituted Methylenecyclopropanes: Facile Access to 6‐(Trifluoromethyl)‐7,8‐Dihydrobenzo[ k ]phenanthridine Derivatives

Author(s) -

Yuan YuChao,

Liu HouLu,

Hu XuBo,

Wei Yin,

Shi Min

Publication year - 2016

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201602920

Subject(s) - phenanthridine , trifluoromethylation , trifluoromethyl , chemistry , visible spectrum , photochemistry , tandem , ring (chemistry) , medicinal chemistry , stereochemistry , organic chemistry , materials science , alkyl , optoelectronics , composite material

A new visible‐light‐induced trifluoromethylation of isonitrile‐substituted methylenecyclopropanes is developed. A range of substituted 6‐(trifluoromethyl)‐7,8‐dihydrobenzo[ k ]phenanthridine derivatives are readily furnished by this newly developed tandem reaction with moderate to good yields. This reaction allows the direct formation of two six‐membered rings and three new C−C bonds, including the C−CF 3 bond, under visible light irradiation.

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