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New 3 D Tubular Porous Structure of an Organic–Zincophosphite Framework with Interesting Gas Adsorption and Luminescence Properties
Author(s) -
Wang ChihMin,
Lee LiWei,
Chang TsungYuan,
Fan BingLun,
Wang ChihLing,
Lin HsiuMei,
Lu KuangLieh
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201602918
Subject(s) - luminescence , adsorption , porosity , chemical engineering , porous medium , materials science , chemistry , organic chemistry , optoelectronics , composite material , engineering
A new 3D tubular zinc phosphite, Zn 2 (C 22 H 22 N 8 ) 0.5 (HPO 3 ) 2 ⋅H 2 O ( 1 ), incorporating a tetradentate organic ligand was synthesized under hydro(solvo)thermal conditions and structurally characterized by single‐crystal X‐ray diffraction. Compound 1 is the first example of inorganic zincophosphite chains being interlinked through 1,2,4,5‐tetrakis(imidazol‐1‐ylmethyl)benzene to form a tubular porous framework with unusual organic–inorganic hybrid channels. The thermal and chemical stabilities, high capacity for CO 2 adsorption compared to that for N 2 adsorption, and interesting optical properties of LED devices fabricated using this compound were also studied.