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Cover Picture: Two Different Pathways in the Reduction of [(S=)PCl(μ‐N t Bu)] 2 with Na (Chem. Eur. J. 34/2016)
Author(s) -
Bawari Deependra,
Prashanth Billa,
Ravi Satyam,
Shamasundar K. R.,
Singh Sanjay,
Wright Dominic S.
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201602881
Subject(s) - chemistry , singlet state , wright , sulfur , reduction (mathematics) , cover (algebra) , crystallography , organic chemistry , computer science , physics , nuclear physics , excited state , programming language , mechanical engineering , geometry , mathematics , engineering
A sulfur‐bridged inorganic macrocycle and a room temperature singlet biradicaloid dianion have been isolated in the Wurtz reduction of a mixture of cis ‐ and trans ‐dichlorophosph(V)azane. It appears that these products from the same reaction are the outcome of two different reduction pathways. This approach may facilitate the discovery of new types of inorganic macrocycles and new polymeric assemblies similar to those observed in this work. More information can be found in the Full Paper by S. Singh, D. S. Wright et al. on page 12027 ff.