Palladium(0)‐Catalyzed Intermolecular Allylic Dearomatization of Indoles by a Formal [4+2] Cycloaddition Reaction | Zendy

Gao RunDuo | Zendy; Xu QingLong | Zendy; Zhang Bo | Zendy; Gu Yiting | Zendy; Dai LiXin | Zendy; You ShuLi | Zendy

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Palladium(0)‐Catalyzed Intermolecular Allylic Dearomatization of Indoles by a Formal [4+2] Cycloaddition Reaction

Author(s) -

Gao RunDuo,

Xu QingLong,

Zhang Bo,

Gu Yiting,

Dai LiXin,

You ShuLi

Publication year - 2016

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201602691

Subject(s) - allylic rearrangement , intermolecular force , chemistry , catalysis , nucleophile , indoline , palladium , alcohol , cycloaddition , allylic alcohol , medicinal chemistry , organic chemistry , molecule

Bridged indoline derivatives were synthesized by an intermolecular Pd‐catalyzed allylic dearomatization reaction of substituted indoles. The reaction between indoles and allyl carbonates bearing a nucleophilic alcohol side‐chain proceeds in a cascade fashion, providing bridged indolines in excellent enantioselectivity.

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