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Kinetically Controlled Assembly of Nitrogen‐Doped Invaginated Carbon Nanospheres with Tunable Mesopores
Author(s) -
Liu Yang,
Zhang Hongwei,
Noonan Owen,
Xu Chun,
Niu Yuting,
Yang Yannan,
Zhou Liang,
Huang Xiaodan,
Yu Chengzhong
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201602672
Subject(s) - supercapacitor , mesoporous material , materials science , chemical engineering , capacitance , carbon fibers , polymerization , ethylenediamine , resorcinol , formaldehyde , nanotechnology , inorganic chemistry , electrode , organic chemistry , chemistry , composite number , catalysis , polymer , composite material , engineering
Mesoporous hollow carbon nanospheres (MHCS) have been extensively studied owning to their unique structural features and diverse potential applications. A surfactant‐free self‐assembly approach between resorcinol/formaldehyde and silicon alkoxide has emerged as an important strategy to prepare MHCS. Extending such a strategy to other substituted phenols to produce heterogeneous‐atom‐doped MHCS remains a challenge due to the very different polymerization kinetics of various resins. Herein, we report an ethylenediamine‐assisted strategy to control the cooperative self‐assembly between a 3‐aminophenol/formaldehyde resin and silica templates. Nitrogen‐doped mesoporous invaginated carbon nanospheres (N‐MICS) with an N content of 6.18 at %, high specific surface areas (up to 1118 m 2 g −1 ), large pore volumes (2.47 cm 3 g −1 ), and tunable mesopores (3.7–11.1 nm) have been prepared. When used as electrical double‐layer supercapacitors, N‐MICS show a high capacitance of 261 F g −1 , an outstanding cycling stability (≈94 % capacitance retention after 10 000 cycles), and a good rate performance.