Isolation and Ambident Reactivity of a Chlorogermylenoid | Zendy

Suzuki Yuko | Zendy; Sasamori Takahiro | Zendy; Guo JingDong | Zendy; Nagase Shigeru | Zendy; Tokitoh Norihiro | Zendy

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Isolation and Ambident Reactivity of a Chlorogermylenoid

Author(s) -

Suzuki Yuko,

Sasamori Takahiro,

Guo JingDong,

Nagase Shigeru,

Tokitoh Norihiro

Publication year - 2016

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201602601

Subject(s) - reactivity (psychology) , recrystallization (geology) , toluene , chemistry , ion , single crystal , crystallography , diffraction , medicinal chemistry , inorganic chemistry , organic chemistry , geology , physics , optics , medicine , paleontology , alternative medicine , pathology

Treatment of 2,5‐di(3,5‐ tert ‐butylphenyl)‐1‐lithioferrocene with GeCl 2 ⋅dioxane afforded the corresponding chlorogermylenoid that exhibited an ambident reactivity in different solvents; it displayed a behavior characteristic for a dichlorogermylene anion in THF, while it exhibited the typical reactivity of a chlorogermylene in toluene. X‐Ray diffraction analysis of a single crystal of this chlorogermylenoid, obtained from recrystallization in THF, revealed a separated‐ion‐pair structure in the solid state.

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