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Rhodium‐Catalyzed ortho ‐Amidations in the Preparation of Thiadiazine 1‐Oxides
Author(s) -
Cheng Ying,
Dong Wanrong,
Wang Han,
Bolm Carsten
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201602550
Subject(s) - rhodium , catalysis , combinatorial chemistry , chemistry , organic chemistry
Abstract Rhodium‐catalyzed ortho ‐amidations of sulfoximines lead to key intermediates for the preparation of thiadiazine 1‐oxides. Following a straightforward protocol, a variety of synthetically valuable compounds can be obtained, thus circumventing common multistep approaches towards potentially bioactive products.

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