A Selective Rh I ‐Catalyzed Substrate‐Controlled C−C Bond Activation of Benzyl Sulfonamide/Alcohol‐Tethered Alkylidenecyclopropanes | Zendy

Chen Kai | Zendy; Liu JiaXin | Zendy; Tang XiangYing | Zendy; Shi Min | Zendy

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A Selective Rh I ‐Catalyzed Substrate‐Controlled C−C Bond Activation of Benzyl Sulfonamide/Alcohol‐Tethered Alkylidenecyclopropanes

Author(s) -

Chen Kai,

Liu JiaXin,

Tang XiangYing,

Shi Min

Publication year - 2016

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201602366

Subject(s) - azepine , sulfonamide , benzyl alcohol , chemistry , catalysis , substrate (aquarium) , rhodium , alcohol , conjugated system , medicinal chemistry , stereochemistry , organic chemistry , oceanography , polymer , geology

Benzyl sulfonamide/alcohol‐tethered alkylidenecyclopropanes undergo a rhodium‐catalyzed and substrate‐controlled selective C−C bond activation, producing three types of common organic structural units: benzo[c]azepine/oxepines, dihydronaphthalen‐1‐amines, and conjugated dienes. Epoxidation and aromatization of these products to construct two useful compounds have also been achieved.

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