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Small Cation‐Based High‐Performance Energetic Nitraminofurazanates
Author(s) -
Tang Yongxing,
He Chunlin,
Mitchell Lauren A.,
Parrish Damon A.,
Shreeve Jean'ne M.
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201602171
Subject(s) - detonation , thermal stability , ammonium , diffraction , energy density , single crystal , chemistry , inorganic chemistry , crystal (programming language) , crystal structure , thermal , materials science , computational chemistry , crystallography , explosive material , thermodynamics , organic chemistry , physics , engineering physics , computer science , optics , programming language
Large nitramino‐substituted furazan anions were combined with small cations (hydroxylammonium, hydrazinium, and ammonium) to form a series of energetic salts that was fully characterized. The structures of several of the compounds ( 1 a , 2 a , 3 a , and 4 a ) were further confirmed by single‐crystal X‐ray diffraction. Based on their physiochemical properties, such as density, thermal stability, and sensitivity, together with the calculated detonation properties, it was found that they exhibit good detonation performance and have potential application as high‐energy‐density materials.