Rhodium(I)‐Catalyzed Benzannulation of Heteroaryl Propargylic Esters: Synthesis of Indoles and Related Heterocycles | Zendy

Li Xiaoxun | Zendy; Xie Haibo | Zendy; Fu Xiaoning | Zendy; Liu Jitian | Zendy; Wang Haoyuan | Zendy; Xi Baomin | Zendy; Liu Peng | Zendy; Xu Xiufang | Zendy; Tang Weiping | Zendy

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Rhodium(I)‐Catalyzed Benzannulation of Heteroaryl Propargylic Esters: Synthesis of Indoles and Related Heterocycles

Author(s) -

Li Xiaoxun,

Xie Haibo,

Fu Xiaoning,

Liu Jitian,

Wang Haoyuan,

Xi Baomin,

Liu Peng,

Xu Xiufang,

Tang Weiping

Publication year - 2016

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201602088

Subject(s) - rhodium , catalysis , chemistry , benzene , ring (chemistry) , combinatorial chemistry , organic chemistry

A de novo synthesis of a benzene ring allows for the preparation of a diverse range of heterocycles including indoles, benzofurans, benzothiophenes, carbazoles, and dibenzofurans from simple heteroaryl propargylic esters using a unified carbonylative benzannulation strategy. Multiple substituents can be easily introduced to the C4–C7 positions of indoles and related heterocycles.

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