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Inside Cover: Highly Phosphorescent Crystals of Square‐Planar Platinum Complexes with Chiral Organometallic Linkers: Homochiral versus Heterochiral Arrangements, Induced Circular Dichroism, and TD‐DFT Calculations (Chem. Eur. J. 24/2016)
Author(s) -
Sesolis Hugo,
DubarleOffner Julien,
Chan Carmen K. M.,
Puig Emmanuel,
Gontard Geoffrey,
Winter Pierre,
Cooksy Andrew L.,
Yam Vivian W. W.,
Amouri Hani
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201602070
Subject(s) - circular dichroism , chromophore , platinum , phosphorescence , chemistry , enantiomer , luminescence , crystallography , organometallic chemistry , planar chirality , ligand (biochemistry) , photochemistry , stereochemistry , materials science , enantioselective synthesis , crystal structure , catalysis , organic chemistry , optics , physics , optoelectronics , fluorescence , biochemistry , receptor
The enantiomeric relationship of chiral luminescent square‐planar platinum complexes is confirmed by circular dichroism traces, as shown for the functionalized Pt( t ‐Bu 3 terpy) chromophore. The chiral organometallic ligand controls the homochiral or heterochiral solid‐state aggregation through π–π and Pt–Pt interactions. These complexes are highly luminescent in the crystalline state; their photophysical properties arise from solid‐state aggregation. More information can be found in the Communication by V. W. W. Yam, H. Amouri et al. on page 8032 ff.