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Defined Palladium–Phthalimidato Catalysts for Improved Oxidative Amination
Author(s) -
Martínez Claudio,
Muñiz Kilian
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201601128
Subject(s) - palladium , amination , catalysis , oxidative phosphorylation , chemistry , organic chemistry , biochemistry
New palladium(II)–phthalimidato complexes have been synthesized, isolated, and structurally characterized. As demonstrated from over 30 examples, they constitute superior catalysts for oxidative amination reactions of alkenes with phthalimide as the nitrogen source. This work streamlines vicinal difunctionalization of alkenes and provides access to significantly improved and experimentally simplified synthetic protocols.