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Platinum(II) Metallomesogens: New External‐Stimuli‐Responsive Photoluminescence Materials
Author(s) -
Cuerva Cristián,
Campo José A.,
Cano Mercedes,
Lodeiro Carlos
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201601115
Subject(s) - platinum , photoluminescence , materials science , nanotechnology , chemistry , optoelectronics , organic chemistry , catalysis
New dicatenar isoquinoline‐functionalized pyrazoles, [Hpz R( n , n )iq ] (R( n , n )=C 6 H 3 (OC n H 2 n +1 ) 2 ; n =4, 6, 8, 10, 12, 14, 16, 18), have been strategically designed and synthesized to induce mesomorphic and luminescence properties into the corresponding bis(isoquinolinylpyrazolate)platinum(II) complexes [Pt(pz R( n , n )iq ) 2 ]. Thermal studies reveal that all platinum(II) compounds exhibit columnar mesophases over an exceptionally wide temperature range, above 300 °C in most cases. The photophysical behavior was also investigated in solution and in the solid state. As a consequence of the formation of Pt⋅⋅⋅Pt interactions, the weak greenish emission of the platinum derivatives turns bright orange in the mesophase. Additionally, the complexes are sensitive to a great variety of external inputs, such as temperature, mechanical grinding, pressure, solvents, and vapors. On this basis, they are used as dopant agents of a polyvinylpyrrolidone or poly(methyl methacrylate) polymer matrix to achieve stimuli‐responsive thin films.