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Inside Cover: Beyond Clusters: Supramolecular Networks Self‐Assembled from Nanosized Silver Clusters and Inorganic Anions (Chem. Eur. J. 20/2016)
Author(s) -
Wang Zhi,
Li XiaoYu,
Liu LiWei,
Yu SiQi,
Feng ZhenYu,
Tung ChenHo,
Sun Di
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201600767
Subject(s) - cluster (spacecraft) , supramolecular chemistry , ion , linker , chemistry , bridge (graph theory) , cover (algebra) , crystallography , nanotechnology , materials science , crystal structure , computer science , organic chemistry , programming language , operating system , medicine , mechanical engineering , engineering
Beyond clusters : The “large cluster and small bridge” strategy is used to create high‐dimensional silver cluster‐based metal–organic frameworks. Two anion‐templated silver clusters, CO 3 @Ag 20 and SO 4 @Ag 22 , are ingeniously incorporated into a 2D sql lattice and an unprecedented 3D two‐fold interpenetrated dia network, respectively, under mild solvothermal conditions. The dual role of the anions, as internal anion template and external linker, is also demonstrated (see figure). More information can be found in the Full Paper by D. Sun et al. on page 6830 ff.