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Copper‐Catalyzed S−C/S−N Bond Interconversions
Author(s) -
Wen Jian,
Cheng Hanchao,
Dong Shunxi,
Bolm Carsten
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201600661
Subject(s) - amination , chemistry , bond cleavage , catalysis , copper , radical , alkylation , medicinal chemistry , bond , cleavage (geology) , stereochemistry , organic chemistry , materials science , fracture (geology) , economics , composite material , finance
Under an atmosphere of dioxygen, copper‐catalyzed de‐alkylation/amination sequences provide sulfonimidamides from unprotected sulfoximines in moderate to good yields. Mechanistic studies suggest the involvement of radicals in both the C−S bond cleavage and the formation of the new N−S bond.
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