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Design of 2D Porous Coordination Polymers Based on Metallacrown Units
Author(s) -
Atzeri Corrado,
Marchiò Luciano,
Chow Chun Y.,
Kampf Jeff W.,
Pecoraro Vincent L.,
Tegoni Matteo
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201600562
Subject(s) - porosity , coordination polymer , polymer , connection (principal bundle) , architecture , block (permutation group theory) , materials science , crystallography , chemical engineering , polymer chemistry , chemistry , composite material , engineering , geometry , mathematics , structural engineering , art , visual arts
Abstract A 12‐metallacrown‐4 (MC) complex was designed and employed as the building block in the synthesis of coordination polymers, one of which is the first permanently porous MC architecture. The connection of the four‐fold symmetric MC subunits by Cu II nodes led to the formation of 2D layers of metallacrowns. Channels are present in the crystalline architecture, which exhibits permanent porosity manifested in N 2 and CO 2 uptake capacity.