Inside Cover: A Dinuclear Ruthenium‐Based Water Oxidation Catalyst: Use of Non‐Innocent Ligand Frameworks for Promoting Multi‐Electron Reactions (Chem. Eur. J. 28/2015) | Zendy

Laine Tanja M. | Zendy; Kärkäs Markus D. | Zendy; Liao RongZhen | Zendy; Siegbahn Per E. M. | Zendy; Åkermark Björn | Zendy

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Inside Cover: A Dinuclear Ruthenium‐Based Water Oxidation Catalyst: Use of Non‐Innocent Ligand Frameworks for Promoting Multi‐Electron Reactions (Chem. Eur. J. 28/2015)

Author(s) -

Laine Tanja M.,

Kärkäs Markus D.,

Liao RongZhen,

Siegbahn Per E. M.,

Åkermark Björn

Publication year - 2015

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201590123

Subject(s) - catalysis , ruthenium , reactivity (psychology) , ligand (biochemistry) , cover (algebra) , chemistry , metal , combinatorial chemistry , quantum chemical , nanotechnology , photochemistry , materials science , molecule , organic chemistry , engineering , mechanical engineering , biochemistry , receptor , medicine , alternative medicine , pathology

The development of catalysts for the oxidation of water using ligands with a non‐innocent character could potentially be employed for the rational design of efficient water‐oxidation catalysts. In their Full Paper on page 10039 ff. , B. Åkermark, M. D. Kärkäs, R.‐Z. Liao and co‐workers explore the mechanistic details associated with a dinuclear Ru‐based water‐oxidation catalyst. Combining experimental studies and quantum chemical calculations provides insight into the fundamental principles controlling the reactivity of the catalyst, in which metal–ligand cooperation is a vital part.

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