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Inside Back Cover: A Terminal, Fluxional η 4 ‐Benzene Complex with a Thermally Accessible Triplet State is the Primary Photoproduct in the Intercyclobutadiene Haptotropism of (CpCo)phenylenes (Chem. Eur. J. 12/2015)
Author(s) -
Albright Thomas A.,
Drissi Rima,
Gandon Vincent,
Oldenhof Sander,
OlobaWhenu Oluwakemi A.,
Padilla Robin,
Shen Hao,
Vollhardt K. Peter C.,
Vreeken Vincent
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201590045
Subject(s) - benzene , terminal (telecommunication) , chemistry , photochemistry , cover (algebra) , ring (chemistry) , stereochemistry , organic chemistry , engineering , telecommunications , mechanical engineering
Irradiation of CpCo‐complexed linear phenylenes causes the metal to hop to the terminal arene ring, from which it migrates in a stepwise cascade back to the center, as in a waterfall. For more information, see the Communication by P. Vollhardt and co‐workers on page 4546 ff. (Background photo: Falls Creek, Turnagain Arm, Alaska, October 23, 2005; ©Anderson‐Smith).