Premium
Cover Picture: Hydrothermal Synthesis, Structure, and Optical Properties of Two Nanosized Ln 26 @CO 3 (Ln=Dy and Tb) Cluster‐Based Lanthanide–Transition‐Metal–Organic Frameworks (Ln MOFs) (Chem. Eur. J. 8/2015)
Author(s) -
Zhang Yu,
Huang Lian,
Miao Hao,
Wan Hong Xiang,
Mei Hua,
Liu Ying,
Xu Yan
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201590030
Subject(s) - lanthanide , cluster (spacecraft) , metal organic framework , absorption (acoustics) , luminescence , chemistry , transition metal , ion , materials science , crystallography , optoelectronics , catalysis , organic chemistry , adsorption , computer science , programming language , biochemistry , composite material
Once a new high‐nuclearity cluster is obtained the accompanying question is how to make it into extended multi‐dimensional metal–organic frameworks (MOFs), in order to explore their optical properties. In their Full Paper on page 3234 ff. , H. Mei, Y. Xu et al. report two Ln 26 ‐HNic cluster‐based multidimensional MOFs with Ag + or Cu + ions as linkers, of which the rare 4d–4f one shows characteristic luminescence of Tb 3+ and good two‐photon absorption with an absorption coefficient β of 0.06947 cm GM −1 .