Premium
Frontispiece: Entropy‐Driven 1,2‐Type Friedel–Crafts Reaction of Phenols with N ‐ tert ‐Butoxycarbonyl Aldimines
Author(s) -
Kato Masaru,
Hirao Shogo,
Nakano Katsuhiro,
Sato Makoto,
Yamanaka Masahiro,
Sohtome Yoshihiro,
Nagasawa Kazuo
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201585162
Subject(s) - friedel–crafts reaction , aldimine , type (biology) , chemistry , catalysis , organic chemistry , ecology , biology
Friedel–Crafts Reaction Efforts to identify factors that contribute to the attainment of a large magnitude of ΔΔ S ≠ in the Friedel–Crafts reaction and DFT calculations in the transition‐state model shines a light on an area of emerging opportunity to link the ΔΔ S ≠ effect and the molecular structure of the conformationally flexible organocatalysts. For more details, see the Full Paper by K. Nagasawa et al. on page 18606 ff.