Frontispiece: Hetero‐Selective DNA‐Like Duplex Stabilized by Donor–Acceptor Interactions | Zendy

Doi Tetsuya | Zendy; Sakakibara Takumi | Zendy; Kashida Hiromu | Zendy; Araki Yasuyuki | Zendy; Wada Takehiko | Zendy; Asanuma Hiroyuki | Zendy

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Frontispiece: Hetero‐Selective DNA‐Like Duplex Stabilized by Donor–Acceptor Interactions

Author(s) -

Doi Tetsuya,

Sakakibara Takumi,

Kashida Hiromu,

Araki Yasuyuki,

Wada Takehiko,

Asanuma Hiroyuki

Publication year - 2015

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201584562

Subject(s) - random hexamer , pyrene , phosphoramidite , chemistry , duplex (building) , dna , anthraquinone , base pair , stereochemistry , crystallography , oligonucleotide , biochemistry , organic chemistry

DNA Structure Mimics In their Full Paper on page 15974 ff. , H. Asanuma, H. Kashida et al. report the characterization of a novel hetero‐selective DNA‐like duplex of pyrene and anthraquinone pseudo base pairs. Pyrene and anthraquinone moieties were tethered on acyclic D‐threoninol linkers and linked to adjacent residues using standard phosphoramidite chemistry. A pyrene hexamer and an anthraquinone hexamer formed a stable artificial hetero‐duplex without the assistance of natural base pairs.

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