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Frontispiece: Reversible Doping of a Dithienothiophene‐Based Conjugated Microporous Polymer
Author(s) -
Bildirir Hakan,
Osken Ipek,
Ozturk Turan,
Thomas Arne
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201582661
Subject(s) - microporous material , conjugated microporous polymer , doping , conjugated system , polymer , materials science , chemical engineering , polymer chemistry , nanotechnology , polymer science , optoelectronics , composite material , engineering
Conjugated Porous Networks Dithienothiophene (DTT) based conjugated microporous polymers (CMPs) were synthesized by bulk and electrochemical oxidative polymerizations. The network exhibits high permanent surface areas of 790 m 2 g −1 and can be reversibly oxidized and reduced, either chemically or electrochemically, accompanied by a significant color change. The introduction of the strong electron donor, DTT, into a conjugated porous network and the ability for redox switching make DTT‐CMPs interesting materials for organo(opto)electronic devices and sensors. For more details see the Communication by T. Ozturk, A. Thomas, and co‐workers on page 9306 ff.