Premium
Back Cover: Multifunctional Tricarbazolo Triazolophane Macrocycles: One‐Pot Preparation, Anion Binding, and Hierarchical Self‐Organization of Multilayers (Chem. Eur. J. 2/2016)
Author(s) -
Lee Semin,
Hirsch Brandon E.,
Liu Yun,
Dobscha James R.,
Burke David W.,
Tait Steven L.,
Flood Amar H.
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201504865
Subject(s) - steric effects , hydrogen bond , stacking , chemistry , ion , carbazole , adsorption , crystallography , supramolecular chemistry , combinatorial chemistry , polymer chemistry , stereochemistry , photochemistry , molecule , organic chemistry , crystal structure
Multifunctional tri(carbazole–triazole) macrocycles were prepared in a one‐pot synthesis. They can be adsorbed from solution onto graphite surfaces and into well‐ordered stacked films under the direction of lateral hydrogen bonding, co‐facial stacking interactions, and steric contacts. Anion‐binding affinity arising from CH hydrogen bonds directed into the central cavity is active in both solution and the adsorbed states; anion‐binding events modify the film structure. More information can be found in the Full Paper by S. L. Tait, A. H. Flood et al. on page 560 ff.