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Enolate Stabilization by Anion–π Interactions: Deuterium Exchange in Malonate Dilactones on π‐Acidic Surfaces
Author(s) -
Miros François N.,
Zhao Yingjie,
Sargsyan Gevorg,
Pupier Marion,
Besnard Céline,
Beuchat César,
Mareda Jiri,
Sakai Naomi,
Matile Stefan
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201504673
Subject(s) - malonate , chemistry , deuterium , cover (algebra) , hydrogen–deuterium exchange , ion , ion exchange , bar (unit) , medicinal chemistry , inorganic chemistry , crystallography , organic chemistry , hydrogen , physics , mechanical engineering , quantum mechanics , meteorology , engineering
Invited for the cover of this issue is the group of Stefan Matile at the University of Geneva. The cover image depicts the crystal structure of a malonate dilactone placed on a chiral π‐acidic surface to measure enolate–π interactions during deuterium exchange. Read the full text of the article at 10.1002/chem.201504008.