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How Does Substitutional Doping Affect Visible Light Absorption in a Series of Homodisperse Ti 11 Polyoxotitanate Nanoparticles—A Comment on the Band Gap Determination of the Fe II Cages ( Chem. Eur. J . 2015, 21 , 11538)
Author(s) -
Matthews Peter D.,
Li Ning,
Luo HeKuan,
Wright Dominic S.
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201504653
Subject(s) - doping , band gap , series (stratigraphy) , absorption (acoustics) , nanoparticle , visible spectrum , materials science , range (aeronautics) , crystallography , optics , chemistry , physics , condensed matter physics , analytical chemistry (journal) , nanotechnology , paleontology , composite material , biology , chromatography
There is no experimental support for the conclusion by Coppens and Chen in a recent paper that the (HOMO–LUMO) band gaps in a series of Fe II polyoxotitanate cages are in the range 1.43–1.59 eV.
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