Premium
Serendipitous Observation of Al I Insertion into a C−O Bond in L 2 PhB (L=Oxazol‐2‐ylidene)
Author(s) -
Kong Lingbing,
Ganguly Rakesh,
Li Yongxin,
Kinjo Rei
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201504537
Subject(s) - carbene , ring (chemistry) , chemistry , medicinal chemistry , oxidative addition , stereochemistry , catalysis , organic chemistry
Oxidative addition of the C−O bond in L 2 PhB: (L=oxazol‐2‐ylidene) to an Al I center induced ring expansion of an oxazol‐2‐ylidene ring, affording a unique organoboron species formally involving either an Al, N, O mixed heterocyclic carbene or anionic (amino)(boryl)carbene fragment.