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Synthesis of Mesoionic Isoquinolines by Rhodium(III)‐Catalyzed C−H Activation
Author(s) -
Zhang Wei,
Wang ChengQi,
Lin Hui,
Dong Lin,
Xu YanJun
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201504245
Subject(s) - mesoionic , annulation , rhodium , isoquinoline , catalysis , chemistry , substrate (aquarium) , combinatorial chemistry , medicinal chemistry , organic chemistry , oceanography , geology
Hydroxyl‐substituted benzaldimines underwent a Rh III ‐catalyzed C−H activation and annulation with alkynes to provide novel mesoionic isoquinoline derivatives in moderate to excellent yields using oxygen as an internal anion source. This simple and efficient approach has a broad substrate scope.
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