Concise Synthesis and Facile Nanotube Assembly of a Symmetrically Multifunctionalized Cycloparaphenylene | Zendy

Miyauchi Yuta | Zendy; Johmoto Kohei | Zendy; Yasuda Nobuhiro | Zendy; Uekusa Hidehiro | Zendy; Fujii Shintaro | Zendy; Kiguchi Manabu | Zendy; Ito Hideto | Zendy; Itami Kenichiro | Zendy; Tanaka Ken | Zendy

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Concise Synthesis and Facile Nanotube Assembly of a Symmetrically Multifunctionalized Cycloparaphenylene

Author(s) -

Miyauchi Yuta,

Johmoto Kohei,

Yasuda Nobuhiro,

Uekusa Hidehiro,

Fujii Shintaro,

Kiguchi Manabu,

Ito Hideto,

Itami Kenichiro,

Tanaka Ken

Publication year - 2015

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201504185

Subject(s) - nanotube , nanotechnology , chemistry , materials science , carbon nanotube

The concise synthesis of C 3 ‐symmetrical [12]CPP‐hexacarboxylate has been achieved through macrocyclization by the rhodium‐catalyzed intermolecular cross‐cyclotrimerization and subsequent reductive aromatization. C 3 ‐Symmetrical functionalization of CPP with highly polar alkoxycarbonyl groups enabled the structurally uniform nanotube assembly in the crystalline state through multiple hydrogen‐bonding interactions giving a dimer followed by one‐dimensional stacking.

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