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Activation and Transformation of Ethane by Au 2 VO 3 + Clusters with Closed‐Shell Electronic Structures
Author(s) -
Li YaKe,
Li ZiYu,
Zhao YanXia,
Liu QingYu,
Meng JingHeng,
He ShengGui
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201503676
Subject(s) - reactivity (psychology) , dehydrogenation , heteronuclear molecule , chemistry , oxide , alkane , dimer , metal , catalysis , molecule , photochemistry , organic chemistry , medicine , alternative medicine , pathology
The study of chemical reactions between gold‐containing heteronuclear oxide clusters and small molecules can provide molecular level mechanisms to understand the excellent activity of gold supported by metal oxides. While the promotion role of gold in alkane transformation was identified in the clusters with atomic oxygen radicals (O −. ), the role of gold in the systems without O −. is not clear. By employing mass spectrometry and quantum chemistry calculations, the reactivity of Au 2 VO 3 + clusters with closed‐shell electronic structures toward ethane was explored. Both the dehydrogenation and ethene elimination channels were identified. It is gold rather than oxygen species initiating the C−H activation. The Au−Au dimer formed during the reactions plays important roles in ethane transformation. The reactivity comparison between Au 2 VO 3 + and bare Au 2 + demonstrates that Au 2 VO 3 + not only retains the property of bare Au 2 + that transforming ethane to dihydrogen, but also exhibits new functions in converting ethane to ethene, which reveals the importance of the composite system. This study provides a further understanding of the reactivity of metal oxide supported gold in alkane activation and transformation.