The Cage Structure of IndanCHF 3  is Based on the Cooperative Effects of CH⋅⋅⋅π and CH⋅⋅⋅F Weak Hydrogen Bonds | Zendy

Favero Laura B. | Zendy; Li Weixing | Zendy; Spada Lorenzo | Zendy; Evangelisti Luca | Zendy; Visentin Giorgio | Zendy; Caminati Walther | Zendy

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The Cage Structure of IndanCHF 3 is Based on the Cooperative Effects of CH⋅⋅⋅π and CH⋅⋅⋅F Weak Hydrogen Bonds

Author(s) -

Favero Laura B.,

Li Weixing,

Spada Lorenzo,

Evangelisti Luca,

Visentin Giorgio,

Caminati Walther

Publication year - 2015

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201502981

Subject(s) - hydrogen bond , benzene , supersonic speed , chemistry , cage , hydrogen , computational chemistry , crystallography , chemical physics , thermodynamics , physics , mathematics , molecule , organic chemistry , combinatorics

The structural and energetic features of the CH⋅⋅⋅π interaction and the internal dynamics of the CHF 3 group change drastically in going from benzeneCHF 3 to indanCHF 3 , according to the analysis of the rotational spectrum of the latter complex generated in a supersonic expansion.

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