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The Cage Structure of IndanCHF 3 is Based on the Cooperative Effects of CH⋅⋅⋅π and CH⋅⋅⋅F Weak Hydrogen Bonds
Author(s) -
Favero Laura B.,
Li Weixing,
Spada Lorenzo,
Evangelisti Luca,
Visentin Giorgio,
Caminati Walther
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201502981
Subject(s) - hydrogen bond , benzene , supersonic speed , chemistry , cage , hydrogen , computational chemistry , crystallography , chemical physics , thermodynamics , physics , mathematics , molecule , organic chemistry , combinatorics
Abstract The structural and energetic features of the CH⋅⋅⋅π interaction and the internal dynamics of the CHF 3 group change drastically in going from benzeneCHF 3 to indanCHF 3 , according to the analysis of the rotational spectrum of the latter complex generated in a supersonic expansion.