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Nanometrization of Lanthanide‐Based Coordination Polymers
Author(s) -
Neaime Chrystelle,
Daiguebonne Carole,
Calvez Guillaume,
Freslon Stéphane,
Bernot Kevin,
Grasset Fabien,
Cordier Stéphane,
Guillou Olivier
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201502906
Subject(s) - lanthanide , luminescence , materials science , polymer , nanoparticle , dynamic light scattering , ethylene glycol , solvent , luminophore , microcrystalline , chemical engineering , polymer chemistry , chemistry , inorganic chemistry , ion , crystallography , nanotechnology , organic chemistry , composite material , engineering , optoelectronics
Heteronuclear lanthanide‐based coordination polymers are microcrystalline powders, the luminescence properties of which can be precisely tuned by judicious choice of the rare‐earth ions. In this study, we demonstrate that such materials can also be obtained as stable solutions of nanoparticles in non‐toxic polyols. Bulk powders of the formula [Ln 2−2 x Ln′ 2 x (bdc) 3 ⋅ 4 H 2 O] ∞ (where H 2 bdc denotes 1,4‐benzene‐dicarboxylic acid, 0≤ x ≤1, and Ln and Ln′ denote lanthanide ions of the series La to Tm plus Y) afford nanoparticles that have been characterized by dynamic light‐scattering (DLS) and transmission electron microscopy (TEM) measurements. Their luminescence properties are similar to those of the bulk materials. Stabilities versus time and versus dilution with another solvent have been studied. This study has revealed that it is possible to tune the size of the nanoparticles. This process offers a reliable means of synthesizing suspensions of nanoparticles with tunable luminescence properties and tunable size distributions in a green solvent (glycerol). The process is also extendable to other coordination polymers and other solvents (ethylene glycol, for example). It constitutes a new route for the facile solubilization of lanthanide‐based coordination polymers.