Catalytic Enantioselective Decarboxylative Allylations of a Mixture of Allyl Carbonates and Allyl Esters: Total Synthesis of (−)‐ and (+)‐Folicanthine | Zendy

Ghosh Santanu | Zendy; Chaudhuri Saikat | Zendy; Bisai Alakesh | Zendy

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Catalytic Enantioselective Decarboxylative Allylations of a Mixture of Allyl Carbonates and Allyl Esters: Total Synthesis of (−)‐ and (+)‐Folicanthine

Author(s) -

Ghosh Santanu,

Chaudhuri Saikat,

Bisai Alakesh

Publication year - 2015

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201502878

Subject(s) - enantioselective synthesis , total synthesis , enol , chemistry , catalysis , organic chemistry

A highly enantioselective decarboxylative allylation of a mixture of enol carbonates and allyl esters has been achieved. The strategic viability of this methodology has been demonstrated through the total synthesis of cyclotryptamine alkaloids (−)‐ and (+)‐folicanthine ( 1 a ) and the formal total synthesis of (−)‐chimonanthine ( 1 b ), (+)‐calycanthine ( 1 c ), and (−)‐ditryptophenaline ( 1 d ).

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