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Coordination Chemistry of Homoleptic Actinide(IV)–Thiocyanate Complexes
Author(s) -
Carter Tyler J.,
Wilson Richard E.
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201502770
Subject(s) - homoleptic , thiocyanate , chemistry , coordination sphere , acetonitrile , actinide , coordination complex , ligand (biochemistry) , inner sphere electron transfer , inorganic chemistry , metal , coordination number , rhenium , neptunium , crystallography , medicinal chemistry , ion , crystal structure , organic chemistry , biochemistry , receptor
Abstract The synthesis, X‐ray crystal structure, vibrational and optical spectroscopy for the eight‐coordinate thiocyanate compounds, [Et 4 N] 4 [Pu IV (NCS) 8 ], [Et 4 N] 4 [Th IV (NCS) 8 ], and [Et 4 N] 4 [Ce III (NCS) 7 (H 2 O)] are reported. Thiocyanate was found to rapidly reduce plutonium to Pu III in acidic solutions (pH<1) in the presence of NCS − . The optical spectrum of [Et 4 N][SCN] containing Pu III solution was indistinguishable from that of aquated Pu III suggesting that inner‐sphere complexation with [Et 4 N][SCN] does not occur in water. However, upon concentration, the homoleptic thiocyanate complex [Et 4 N] 4 [Pu IV (NCS) 8 ] was crystallized when a large excess of [Et 4 N][NCS] was present. This compound, along with its U IV analogue, maintains inner‐sphere thiocyanate coordination in acetonitrile based on the observation of intense ligand‐to‐metal charge‐transfer bands. Spectroscopic and crystallographic data do not support the interaction of the metal orbitals with the ligand π system, but support an enhanced An IV –NCS interaction, as the Lewis acidity of the metal ion increases from Th to Pu.