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A Stable Seven‐Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle
Author(s) -
Kalita Hemanta,
Lee WayZen,
Theophall Gregory G.,
Lakshmi K. V.,
Ravikanth M.
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201501889
Subject(s) - electrochemistry , chemistry , crystallography , stereochemistry , electrode
Unprecedented examples of smaragdyrin macrocycles containing seven membered heterocyclic rings were synthesized under simple reaction conditions in high yields. The heterocycle formed inside smaragdyrin macrocycle is rare example of heterocycle containing five different atoms, such as B, C, N, O, and P atoms. The mixed B III and P V complexes of smaragdyrin macrocycles showed new structural, spectral, and electrochemical properties.