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Synthesis and Thorough Investigation of Discrete Organotin Telluride Clusters
Author(s) -
Eußner Jens P.,
Kusche Ralph O.,
Dehnen Stefanie
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201501666
Subject(s) - tin , derivatization , telluride , chemistry , core (optical fiber) , materials science , combinatorial chemistry , organic chemistry , high performance liquid chromatography , composite material
Systematic experimental and theoretical investigations of reactions of R 1 SnCl 3 (R 1 =CMe 2 CH 2 C(Me)O) with (Me 3 Si) 2 Te allowed for the stepwise formation and single‐crystalline isolation of the first tin sesquitelluride clusters with functional organic ligands. Subsequent derivatization of the latter took place under reorganization of the inorganic core, affording clusters with complex hybrid architectures.