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Synthesis and Coordination Chemistry of Iminophosphanes
Author(s) -
van Dijk Tom,
Burck Sebastian,
Rosenthal Amos J.,
Nieger Martin,
Ehlers Andreas W.,
Slootweg J. Chris,
Lammertsma Koop
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201501126
Subject(s) - denticity , iridium , rhodium , chemistry , imine , coordination complex , ion , crystal structure , group (periodic table) , stereochemistry , crystallography , catalysis , organic chemistry , metal
Abstract Iminophosphanes are a new group of 1,3‐P,N‐ligands, readily obtainable from secondary phosphanes and nitrilium ions, having a tunable N‐donor site by means of varying the imine substituents. These ligands give, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes. Crystal structures are reported for both the ligands and the complexes.