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Aluminum Redistribution during the Preparation of Hierarchical Zeolites by Desilication
Author(s) -
Mitchell Sharon,
Milina Maria,
Verel René,
HernándezRodríguez Manuel,
Pinar Ana B.,
McCusker Lynne B.,
PérezRamírez Javier
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201500992
Subject(s) - calcination , zeolite , mesoporous material , catalysis , redistribution (election) , materials science , synchrotron , characterization (materials science) , chemical engineering , aluminium , inorganic chemistry , nanotechnology , chemistry , organic chemistry , metallurgy , physics , political science , engineering , politics , nuclear physics , law
A literature survey reveals a prominent reduction in the concentration of Brønsted acid sites in hierarchically organized zeolites with increasing mesoporous or external surface area independent of the framework type or synthesis route; this suggests a common fundamental explanation. To determine the cause, nature, and impact of the underlying changes in aluminum speciation, this study combines a multitechnique analysis that integrates basic characterization, a detailed synchrotron XRD and multiple‐quantum NMR spectroscopy assessment, and catalytic tests to correlate evolution of the properties with performance during successive steps in the preparation of hierarchical MFI‐type zeolites by desilication. The findings, subsequently generalized to FAU‐ and BEA‐type materials, identify the crucial impact of calcination on the protonic form, which is an integral step in the synthesis and regeneration of zeolite catalysts; on aluminum coordination; and the associated acidity trends.