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Highly Active, Chemo‐ and Regioselective Yb II and Sm II Catalysts for the Hydrophosphination of Styrene with Phenylphosphine
Author(s) -
Basalov Ivan V.,
Dorcet Vincent,
Fukin Georgy K.,
Carpentier JeanFrançois,
Sarazin Yann,
Trifonov Alexander A.
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201500380
Subject(s) - styrene , regioselectivity , phenylphosphine , catalysis , chemistry , solvent , polymer chemistry , medicinal chemistry , nuclear chemistry , organic chemistry , copolymer , phosphine , polymer
Stable heteroleptic amido Yb II and Sm II complexes bearing aminoether–phenolate ligands and devoid of coordinated solvent have been structurally characterized. They afford highly active, chemoselective and, in the case of monoadditions, 100 % anti‐Markovnikov regiospecific catalysts (down to 0.04 mol % loading) for the hydrophosphination of styrene with PhPH 2 under mild conditions.