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Room Temperature CP Bond Formation Enabled by Merging Nickel Catalysis and Visible‐Light‐Induced Photoredox Catalysis
Author(s) -
Xuan Jun,
Zeng TingTing,
Chen JiaRong,
Lu LiangQiu,
Xiao WenJing
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201500227
Subject(s) - catalysis , photoredox catalysis , nickel , photochemistry , chemistry , aryl , visible spectrum , substrate (aquarium) , combinatorial chemistry , photocatalysis , organic chemistry , materials science , alkyl , oceanography , optoelectronics , geology
A novel and efficient CP bond formation reaction of diarylphosphine oxides with aryl iodides was achieved by combining nickel catalysis and visible‐light‐induced photoredox catalysis. This dual‐catalytic reaction showed a broad substrate scope, excellent functional group tolerance, and afforded the corresponding products in good to excellent yields. Compared with the previously reported use of photoredox/nickel dual catalysis in the construction of CC bonds, the methodology described herein was observed to be the first to allow for C‐heteroatom bond formation.